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By F.G.A. Stone, Robert West (Eds.)

ADVANCES ORGANOMETALLIC CHEMISTRY V12. content material: bankruptcy 7. The Literature of Organo-Transition steel Chemistry 1972Author Index: experiences of Organo-Transition steel Chemistry; writer Index; topic Index; Cumulative record of individuals; Cumulative checklist of Titles. summary: ADVANCES ORGANOMETALLIC CHEMISTRY V12

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318 (1962). 19. , J. Inorg. Nucl. Chem. 8, 515 (1958). 20. , Coffey, R. , and Thompson, D. , J. Chem. ,A 190 (1968), and references therein. 21. , and Davidson, J. , J. Chem. 2433 (1964), and references therein. 22. , and Davidson, J. , J. Chem. 843 (1965). 23. , Duncanson, L. , Shaw, B. , and Venanzi, L. Dis. 26,131 (1958),and references therein. 24. , Duncanson, L. , and Shaw, B. , Proc. Chem. , and Shaw, B. , J. Chem. 5075 (1962). 25. , Guy, R. , Duncanson, L. , and Thompson, D. , J. Chem. SOC.

C. Formed by Splitting a C-C Bond Following suggestions by Walsh (69) that there is considerable delocalization of electrons in the cyclopropane ring, Tipper (67) prepared a substance “ cyclopropaneplatinous chloride,” of formula PtCl,(C,H,), from which cyclopropane was regenerated on reaction with potassium cyanide. ” However, it gave a pyridine derivative [PtCl,(py)z(C,H,),] whose stereo-chemistry is not in accord with platinum(I1) chemistry. This prompted reinvestigation (3)which showed it to be a platinacyclobutane(1V) derivative (X), converted to a mononuclear octahedral complex [PtCl,(-CH,-CH,-CH,-)(py)z] on 20 JOSEPH C H A T reaction with pyridine.

Ginsberg, A. , Trunrition Metal Chem. 1, 122 (Table 3) (1965). Goddard, A. , in “A Text Book of Inorganic Chemistry” (J. ), Vol. XI, Parts I-IV. Griffin, London, 1928-1937. , Nutumissmchuften 19, 360 (1931). , Aduun. Orgunometal. Chem. 8, 1 (1970). Hofmann, K. , Ber. 41,1625 (1908). Keller, R. , Chem. Rev. 28,229 (1941). Longuet-Higgins, H. , and Orgel, L. , J. Chem. 1969 (1956). Maitlis, P. , and Games, M. , J. Amer. Chem. SOC. 85, 1887 (1963). Maitlis, P. , “The Organic Chemistry of Palladium,” Vol.

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