Download Activation and Functionalization of C—H Bonds by Karen I. Goldberg and Alan S. Goldman (Eds.) PDF

By Karen I. Goldberg and Alan S. Goldman (Eds.)

Content material: 1. Organometallic C-H bond activation : an creation / Alan S. Goldman and Karen I. Goldberg -- 2. C-H bond activation through iridium and rhodium complexes : catalytic hydrogen-deuterium trade and C-C bond-forming reactions / Steven R. Klei, Kian L. Tan, Jeffrey T. Golden, Cathleen M. Yung, Reema okay. Thalji, Kateri A. Ahrendt, Jonathan A. Ellman, T. Don Tilley and Robert G. Bergman

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ACS Symposium Series; American Chemical Society: Washington, DC, 2004. ch001 olefin insertion into M - R bonds), such complexes would seem to offer promise with respect to catalytic insertion of olefins into C - H bonds. A n early indication of such promise was the report by Jordan of the insertion of propene into the C H bond of 2-picoline (eq 37) (143). Very recently, Tilley has found that C p * S c C H catalyzes (albeit with low turnovers) the addition of methane across the propene C - H bond to give isobutane (144).

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